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Synthesis and Properties of Chlorotris (1,3-Dibenzylimidazolidin-2-ylidene) Rhodium (I) and of Some Related Compounds

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Advances in Metal Carbene Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 269))

Abstract

The electron-rich alkene (R = CH2Ph) has been used as a source of various carbenerhodium(I) complexes: [RhC](cod)(L)] (1), [RhCl(L)3] (2), [RhCl(CO)(h)3] (3), and trans-[RhCl(CO)(L)2] (4), and of the iridium(I) complex [IrCl(L)3] (5). Compounds (2) and (5) are of particular interest as they contain no other neutral ligand apart from the carbene: (R = CH2Ph); their chemistry is in many ways related to that of the well known complexes [MCl(PPh3)3] (M = Rh or Ir). Thus, compound (2) readily loses a carbene ligand upon treatment with either carbon monoxide [ultimately to lead to (4)], or O2 to yield a compound tentatively formulated as [RhCl(L)2(O2)] (6). The x-ray structures of complexes (2) and (4) have been determined.

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References

  1. M.F. Lappert, J. Organomet. Chem., 1988,

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Author information

Authors and Affiliations

  1. Fen-Edebiyat Fakültesi, Inönü Universitesi, Malatya, 44069, Turkey

    Bekir Cetinkaya

  2. School of Chemistry and Molecular Sciences, University of Sussex, Brighton, BN1 9QJ, UK

    Peter B. Hitchcock, Hatam A. Jasim & Michael F. Lappert

Authors
  1. Bekir Cetinkaya
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  2. Peter B. Hitchcock
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  3. Hatam A. Jasim
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  4. Michael F. Lappert
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Editor information

Editors and Affiliations

  1. Institute for Inorganic Chemistry, University of Würzburg, Würzburg, Germany

    U. Schubert

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© 1989 Kluwer Academic Publishers

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Cetinkaya, B., Hitchcock, P.B., Jasim, H.A., Lappert, M.F. (1989). Synthesis and Properties of Chlorotris (1,3-Dibenzylimidazolidin-2-ylidene) Rhodium (I) and of Some Related Compounds. In: Schubert, U. (eds) Advances in Metal Carbene Chemistry. NATO ASI Series, vol 269. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2317-1_6

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  • DOI: https://doi.org/10.1007/978-94-009-2317-1_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7541-1

  • Online ISBN: 978-94-009-2317-1

  • eBook Packages: Springer Book Archive

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